Why some bubbles move faster

Date:
March 3, 2022
Source:
Graz University of Technology
Summary:
Why do large gas bubbles in viscoelastic liquids (such as polymer
and protein solutions) rise so much faster than expected? An
open question with great relevance for industrial production
processes. Researchers have now found an explanation.



FULL STORY ==========================================================================
It is a puzzle long known among experts and very relevant in many
industrial production processes: a jump discontinuity in the rise
velocity of gas bubbles in so-called viscoelastic fluids. Viscoelastic
fluids are substances that combine characteristics of liquid and elastic substances. Many hair shampoos are an example of this. If you turn a transparent, almost completely filled bottle of shampoo upside down,
you will see the enclosed air rising as a bubble in an unusual shape. In
many industrial processes, such liquids occur as solutions of polymers
and often have to be enriched with oxygen by gassing. "We have known
for about 60 years that the rise velocity of gas bubbles in viscoelastic liquids undergoes a jump at a critical bubble diameter. The speed of the bubbles can then suddenly become up to ten times faster. This plays a fundamental role in the controlled gassing of these liquids. At the same
time, it was unclear what was causing this sudden increase in velocity," explains Gu"nter Brenn from the Institute of Fluid Mechanics and Heat
Transfer at TU Graz.


==========================================================================
With a combination of simulation, experiment and theoretical analysis,
the teams of Gu"nter Brenn at TU Graz and Dieter Bothe at TU Darmstadt
have now solved the puzzle together. They've found that the interaction
of the polymer molecules with the flow around the gas bubbles leads
to the bubbles' strange velocity behaviour. With this knowledge, the
oxygen input into these solutions can now be predicted more accurately,
which means that equipment in biotechnology, process engineering and
the pharmaceutical industry, for example, can be better designed. The researchers currently explain their findings in the Journal of
Non-Newtonian Fluid Mechanics.

"Relaxed" state preferred Polymers often consist of huge molecules that interact in complex ways with the liquid in which they are dissolved. This interaction makes a liquid viscoelastic. What causes the jump in velocity
that gas bubbles display in these liquids from the critical diameter
onwards? Gu"nter Brenn explains the latest findings: "The flow around the bubble causes the dissolved polymer molecules to stretch. The molecules
do not particularly like this state. They want to return to the relaxed, unstretched state as soon as possible." If this return to the relaxed
state is faster than the transport of the molecules to the equator of the bubble, then the bubble remains slow. If, on the other hand, the return to
the relaxed state takes longer than the journey to the bubbles's equator,
then a tension is released in the fluid that "pushes" the bubble. This
leads to a self-amplification, since subsequent polymer molecules position themselves below the equator and relax, unloading their elastic energy, releasing a "propulsive force." In addition to the high practical
relevance of this finding, especially for the above-mentioned areas of application, there are also consequences in basic research. "It turned out
that another surprising property of the flow field of these solutions can
be assigned to this molecular mechanism we showed: namely, the so-called 'negative wake' of the gas bubble," says Dieter Bothe from the Analysis
working group of the Department of Mathematics at TU Darmstadt. This
is an area in the flow field below the bubble where the fluid normally "follows" the bubble at a low velocity. With polymeric liquids, however,
it is the other way round: there, the movement of the liquid is oriented
in the opposite direction to the movement of the bubble. This fluid
movement is caused by the same tension that "pushes" the bubble. This understanding can lead to possibilities for controlling flow processes.

========================================================================== Story Source: Materials provided by
Graz_University_of_Technology. Original written by Susanne
Filzwieser. Note: Content may be edited for style and length.


========================================================================== Related Multimedia:
* Polymer_flow_and_bubble_rise_behavior ========================================================================== Journal Reference:
1. Dieter Bothe, Matthias Niethammer, Christian Pilz, Gu"nter
Brenn. On the
molecular mechanism behind the bubble rise velocity jump
discontinuity in viscoelastic liquids. Journal of Non-Newtonian
Fluid Mechanics, 2022; 302: 104748 DOI: 10.1016/j.jnnfm.2022.104748 ==========================================================================

Link to news story: https://www.sciencedaily.com/releases/2022/03/220303112220.htm

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