Researchers create morphing crystals powered by water evaporation

Date:
September 14, 2020
Source:
Advanced Science Research Center, GC/CUNY
Summary:
New study details the design of materials that enable clean and
sustainable water evaporation energy that can be harvested and
efficiently converted into motion with the potential to power
future mechanical devices and machines.



FULL STORY ========================================================================== Water evaporation, as observed when a puddle of water disappears on
a summer day, is a remarkably powerful process. If it were harnessed,
the process could provide a clean source of energy to power mechanical
machines and devices. In a newly published paper in Nature Materials,
an international team of scientists led by researchers at the Advanced
Science Research Center at the Graduate Center, CUNY (CUNY ASRC)
details the development of shape-shifting crystals that directly convert evaporation energy into powerful motions.


========================================================================== These water-responsive materials were created by using simple variants
of biological building blocks, known as tripeptides, to create crystals
that are simultaneously stiff and morphable. The materials are composed of three- dimensional patterns of nanoscale pores where water tightly binds,
and these pores are interspersed with a molecular network of stiff and
flexible regions.

When humidity is lowered and reaches a critical value, the water escapes
from the pores leading to a powerful contraction of the interconnected
network. This results in the crystals temporarily losing their ordered
patterns until humidity is restored and the crystals regain their original shape. This newly designed process can be repeated over and over and
gives rise to a remarkably efficient method of harvesting evaporation
energy to perform mechanical work.

"We essentially created a new type of actuator, which is driven by water evaporation," said Graduate Center Ph.D. student Roxana Piotrowska,
the study's first author and a researcher at the CUNY ASRC Nanoscience Initiative. "By observing its activity we've been able to identify the fundamental mechanisms of how water-responsive materials can efficiently convert evaporation into mechanical energy." "Our work enables the direct observation of materials' evaporation-driven actuation at the molecular scale,'' said the study's corresponding author Xi Chen, whose lab with
CUNY ASRC Nanoscience Initiative co-led the research. "By learning how
to efficiently extract energy from evaporation, and turn it into motion,
better and more efficient actuators can be designed for many applications, including evaporation energy harvesting devices.'' "Importantly, our
designed crystals are produced from the exact same building blocks that proteins are made of, but they are radically simplified and as a result,
their properties can be precisely tuned and rationally optimized for this application," said CUNY ASRC Nanoscience Initiative Director Rein Ulijn,
whose lab, which co-led the work, is responsible for the biomolecular
design aspects of the research. "The beauty of using biological building
blocks to create this new technology is that the resulting morphogenic
crystals are biocompatible, biodegradable, and cost-effective." By using
a combination of laboratory-based experiments and computer simulations,
the researchers were able to identify and study the factors that control
the actuation of these crystals. This approach resulted in new insights
that inform the design of more efficient ways to use evaporation for
a variety of applications, which may include robotic components or
mechanical micro- and nano-machines that are powered by water evaporation.


========================================================================== Story Source: Materials provided by
Advanced_Science_Research_Center,_GC/CUNY. Note: Content may be edited
for style and length.


========================================================================== Journal Reference:
1. Roxana Piotrowska, Travis Hesketh, Haozhen Wang, Alan R. G. Martin,
Deborah Bowering, Chunqiu Zhang, Chunhua T. Hu, Scott A. McPhee,
Tong Wang, Yaewon Park, Pulkit Singla, Thomas McGlone, Alastair
Florence, Tell Tuttle, Rein V. Ulijn, Xi Chen. Mechanistic insights
of evaporation- induced actuation in supramolecular crystals. Nature
Materials, 2020; DOI: 10.1038/s41563-020-0799-0 ==========================================================================

Link to news story: https://www.sciencedaily.com/releases/2020/09/200914112237.htm

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