Using laser to cool polyatomic molecule

Date:
September 11, 2020
Source:
Harvard University
Summary:
Researchers describe using a novel method combining cryogenic
technology and direct laser light to cool the nonlinear polyatomic
molecule calcium monomethoxide (CaOCH3) to just above absolute zero.



FULL STORY ========================================================================== After firing the lasers and bombarding the molecules with light, the
scientists gathered around the camera to check the results. By seeing
how far these cold molecules expanded they would know almost instantly
whether they were on the right track or not to charting new paths in
quantum science by being the first to cool (aka slow down) a particularly complex, six-atom molecule using nothing but light.


========================================================================== "When we started out on the project we were optimistic but were not sure
that we would see something that would show a very dramatic effect,"
said Debayan Mitra, a postdoctoral researcher in Harvard's Doyle Research Group. "We thought that we would need more evidence to prove that we were actually cooling the molecule, but then when we saw the signal, it was
like, 'Yeah, nobody will doubt that.' It was big and it was right there."
The study led by Mitra and graduate student Nathaniel B. Vilas is the
focus of a new paper published in Science. In it, the group describes
using a novel method combining cryogenic technology and direct laser
light to cool the nonlinear polyatomic molecule calcium monomethoxide
(CaOCH3) to just above absolute zero.

The scientists believe their experiment marks the first time such a
large complex molecule has been cooled using laser light and say it
unlocks new avenues of study in quantum simulation and computation,
particle physics, and quantum chemistry.

"These kinds of molecules have structure that is ubiquitous in chemical
and biological systems," said John M. Doyle, the Henry B. Silsbee
Professor of Physics and senior author on the paper. "Controlling
perfectly their quantum states is basic research that could shed light
on fundamental quantum processes in these building blocks of nature."
The use of lasers to control atoms and molecules -- the eventual building- blocks of a quantum computer -- has been used since the 1960s and has
since revolutionized atomic, molecular, and optical physics.



==========================================================================
The technique essentially works by firing a laser at them, causing the
atoms and molecules to absorb the photons from the light and recoil in
the opposite direction. This eventually slows them down and even stops
them in their tracks.

When this happens quantum mechanics becomes the dominant way to describe
and study their motion.

"The idea is that on one end of the spectrum there are atoms that have
very few quantum states," Doyle said. Because of this, these atoms are
easy to control with light since they often remain in the same quantum
state after absorbing and emitting light, he said. "With molecules they
have motion that does not occur in atoms -- vibrations and rotations. When
the molecule absorbs and emits light this process can sometimes make the molecule spin around or vibrate internally. When this happens, it is now
in a different quantum state and absorbing and emitting light no longer
works [to cool it]. We have to 'calm the molecule down,' get rid of its
extra vibration before it can interact with the light the way we want." Scientists -- including those from the Doyle Group which is part of the
Harvard Department of Physics and a member of the Harvard-MIT Center for Ultracold Atoms -- have been able to cool a number of molecules using
light, such as diatomic and triatomic molecules which each have two or
three atoms.

Polyatomic molecules, on the other hand, are much more complex and have
proven much more difficult to manipulate because of all the vibrations
and rotations.

To get around this, the group used a method they pioneered to cool
diatomic and triatomic molecules. Researchers set up up a sealed cryogenic chamber where they cooled helium to below four Kelvin (that's close to
450 degrees below zero in Fahrenheit). This chamber essentially acts
as a fridge. It's this fridge where the scientists created the molecule
CaOCH3. Right off the bat, it was already moving at a much slower velocity
than it would normally, making it ideal for further cooling.



==========================================================================
Next came the lasers. They turned on two beams of light coming at the
molecule from opposing directions. These counterpropagating lasers
prompted a reaction known as Sisyphus cooling. Mitra says the name is
fitting since in Greek mythology Sisyphus is punished by having to roll
a giant boulder up a hill for eternity, only for it to roll back down
when he nears the top.

The same principle happens here with molecules, Mitra said. When two
identical laser beams are firing in opposite directions, they form a
standing wave of light. There are places where the light is less intense
and there are places where it is stronger. This wave is what forms a metaphorical hill for the molecules.

The "molecule starts at the bottom of a hill formed by the
counter-propagating laser beams and it starts climbing that hill just
because it has some kinetic energy in it and as it climbs that hill,
slowly, the kinetic energy that was its velocity gets converted into
potential energy and it slows down and slows down and slows down until
it gets to the top of the hill where it's the slowest," he said.

At that point, the molecule moves closer to a region where the light
intensity is high, where it will more likely absorb a photon and rolls
back down to the opposite side. "All they can do is keep doing this
again and again and again," Mitra said.

By looking at images from cameras placed outside the sealed chamber,
the scientists then inspect how much a cloud of these molecules expands
as it travels through the system. The smaller the width of the cloud,
the less kinetic energy it has -- therefore the colder it is.

Analyzing the data further, they saw just how cold. They took it from 22 milikelvin to about 1 milikelvin. In other words, just a few thousandths
of a decimal above absolute zero.

In the paper, the scientists lay out ways get the molecule even colder
and lay out some of the doors it opens in a range of modern physical
and chemical research frontiers. The scientists explain, the study is a
proof of concept that their method could be used to cool other carefully
chosen complex molecules to help advance quantum science.

"What we did here is sort of extending the state of the art," Mitra
said. "It's always been debated whether we would ever have technology
that will be good enough to control complex molecules at the quantum
level. This particular experiment is just a stepping stone."

========================================================================== Story Source: Materials provided by Harvard_University. Original written
by Juan Siliezar.

Note: Content may be edited for style and length.


========================================================================== Journal Reference:
1. Debayan Mitra, Nathaniel B. Vilas, Christian Hallas, Loi"c Anderegg,
Benjamin L. Augenbraun, Louis Baum, Calder Miller, Shivam Raval,
John M.

Doyle. Direct laser cooling of a symmetric top molecule. Science,
2020; 369 (6509): 1366 DOI: 10.1126/science.abc5357 ==========================================================================

Link to news story: https://www.sciencedaily.com/releases/2020/09/200911141736.htm

--- up 2 weeks, 4 days, 6 hours, 50 minutes
* Origin: -=> Castle Rock BBS <=- Now Husky HPT Powered! (1337:3/111)