Making plastic more transparent while also adding electrical
conductivity

Date:
July 6, 2020
Source:
University of Michigan
Summary:
In an effort to improve large touchscreens, LED light panels and
window- mounted infrared solar cells, researchers have made plastic
conductive while also making it more transparent.



FULL STORY ==========================================================================
In an effort to improve large touchscreens, LED light panels and
window-mounted infrared solar cells, researchers at the University
of Michigan have made plastic conductive while also making it more
transparent.


==========================================================================
They provide a recipe to help other researchers find the best balance
between conductivity and transparency by creating a three-layer
anti-reflection surface. The conductive metal layer is sandwiched between
two "dielectric" materials that allow light to pass through easily. The dielectrics reduce the reflection from both the plastic and metal layer
between them.

"We developed a way to make coatings with high transparency and
conductivity, low haze, excellent flexibility, easy fabrication and great compatibility with different surfaces," said Jay Guo, U-M professor of electrical engineering and computer science, who led the work.

Previously, Guo's team had shown that it was possible to add a layer of
metal onto a plastic sheet to make it conductive -- a very thin layer of
silver that, by itself, reduced the transmission of light by roughly 10%.

Light transmission through plastic is a little lower than through glass,
but its transparency can be improved with anti-reflection coatings. Guo
and his colleague Dong Liu, a visiting professor at U-M from Nanjing
University of Science and Technology, realized that they could make an anti-reflection coating that was also conductive.

"It was taken for granted that the transmittance of the conductor is
lower than that of the substrate, but we show that this is not the case,"
said Chengang Ji, first author of the study in Nature Communications,
who worked on the project as a Ph.D. student in electrical and computer engineering. Ji received his doctorate from U-M in 2019.

The dielectrics chosen by the team in this case are aluminum oxide
and zinc oxide. On the side closest to the light source, the aluminum
oxide reflects less light back to the source than the plastic surface
would. Then comes the metal layer, composed of silver with a tiny amount
of copper in it, just 6.5 nanometers thick, and then zinc oxide helps
guide the light into the plastic surface. Some light still gets reflected
back where the plastic meets the air on the opposite side, but overall,
the light transmission is better than the plastic alone. The transmittance
is 88.4%, up from 88.1% for the plastic alone.

With the theory results, the team anticipates that other researchers will
be able to design similar sandwich-style flexible, highly transparent conductors, which allow even more light through than the plastic alone.

"We tell people how transparent a dielectric-metal-dielectric conductor
could be, for a target electrical conductance. We also tell them how to
achieve this high transmittance step-by-step," Liu said.

The tricks are selecting the right dielectrics and then figuring out
the right thickness for each to suppress the reflection of the thin
metal. In general, the material between the plastic and metal should
have a higher refractive index, while the material nearest the display
or light source should have a lower refractive index.

Guo is continuing to move the technology forward, collaborating on a
project that uses transparent conductors in solar cells for mounting on windows. These could absorb infrared light and convert it to electricity
while leaving the visible spectrum to brighten the room. He also proposes
large panel interactive displays and car windshields that can melt ice
the way rear windows can.


========================================================================== Story Source: Materials provided by University_of_Michigan. Original
written by Kate McAlpine. Note: Content may be edited for style and
length.


========================================================================== Journal Reference:
1. Chengang Ji, Dong Liu, Cheng Zhang, L. Jay
Guo. Ultrathin-metal-film-
based transparent electrodes with relative transmittance surpassing
100%.

Nature Communications, 2020; 11 (1) DOI: 10.1038/s41467-020-17107-6 ==========================================================================

Link to news story: https://www.sciencedaily.com/releases/2020/07/200706140903.htm

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